Radiometric Correction of Observations from Microwave Humidity Sounders

The Advanced Microwave Sounding Unit-B (AMSU-B) and Microwave Humidity Sounder (MHS) are total power microwave radiometers operating at frequencies near the water vapor absorption line at 183 GHz. The measurements of these instruments are crucial for deriving a variety of climate and hydrological products such as water vapor, precipitation, and ice cloud parameters. However, these measurements are subject to several errors that can be classified into radiometric and geometric errors. The aim of this study is to quantify and correct the radiometric errors in these observations through intercalibration. Since the bias in the calibration of microwave instruments changes with scene temperature, a two-point intercalibration correction scheme was developed based on averages of measurements over the tropical oceans and nighttime polar regions. The intercalibration coefficients were calculated on a monthly basis using measurements averaged over each specified region and each orbit, then interpolated to estimate the daily coefficients. Since AMSU-B and MHS channels operate at different frequencies and polarizations, the measurements from the two instruments were not intercalibrated. Because of the negligible diurnal cycle of both temperature and humidity fields over the tropical oceans, the satellites with the most stable time series of brightness temperatures over the tropical oceans (NOAA-17 for AMSU-B and NOAA-18 for MHS) were selected as the reference satellites and other similar instruments were intercalibrated with respect to the reference instrument. The results show that channels 1, 3, 4, and 5 of AMSU-B on board NOAA-16 and channels 1 and 4 of AMSU-B on board NOAA-15 show a large drift over the period of operation. The MHS measurements from instruments on board NOAA-18, NOAA-19, and MetOp-A are generally consistent with each other. Because of the lack of reference measurements, radiometric correction of microwave instruments remain a challenge, as the intercalibration of these instruments largely depends on the stability of the reference instrument

The Relationship Between Task Cohesion and Competitive State Anxiety

The general purpose of the present study was to determine if perceptions of team cohesion are related to the interpretation athletes attach to their precompetition anxiety. Specifically examined was the association between athlete perceptions of task cohesiveness (Individual Attractions to the Group–Task, ATG-T, and Group Integration–Task, GI-T) and the degree to which perceptions of the intensity of precompetition anxiety symptoms (cognitive and somatic) were viewed as facilitative versus debilitative. Participants were athletes (N = 392) from the sports of soccer, rugby, and field hockey. Each athlete completed the Group Environment Questionnaire (Carron, Widmeyer, & Brawley, 1985) after a practice session. A directionally modified version of the Competitive State Anxiety Inventory-2 (Martens, Burton, Vealey, Bump, & Smith, 1990) was completed just prior to a competition. Results showed that athletes who perceived their cognitive anxiety as facilitative had higher perceptions of both ATG-T and GI-T, χ2 (2, N = 260) = 8.96, p \u3c .05, than athletes who perceived their cognitive anxiety as debilitative. Also, athletes who perceived their somatic anxiety as facilitative had higher perceptions of GI-T, χ2 (2, N = 249) = 5.85, p \u3c .05

Baccharis Malibuensis (Asteraceae): A New Species from the Santa Monica Mountains, California

Baccharis malibuensis is described from the Malibu Lake region of the Santa Monica Mountains, Los Angeles County, California. It is closely related to Baccharis plummerae subsp. plummerae but differs in having narrow, subentire, typically conduplicate, sparsely villous to mostly glabrous leaves with glands occurring in depressions on the adaxial surface, more cylindrical inflorescences, and a distribution in open chaparral vegetation. The new taxon shares some characteristics with B. plummerae subsp. glabrata of northwestern San Luis Obispo County, e.g., smaller leaves, reduced vestiture, and occurrence in scrub habitat, but the two taxa appear to have developed independently from B. p. subsp. plummerae. As the new taxon is morphologically recognizable, occurs in a different habitat, and exhibits no introgression with subsp. plummerae, it is recognized as a distinct species

A Comprehensive Spectroscopic Analysis of DB White Dwarfs

We present a detailed analysis of 108 helium-line (DB) white dwarfs based on model atmosphere fits to high signal-to-noise optical spectroscopy. We derive a mean mass of 0.67 Mo for our sample, with a dispersion of only 0.09 Mo. White dwarfs also showing hydrogen lines, the DBA stars, comprise 44% of our sample, and their mass distribution appears similar to that of DB stars. As in our previous investigation, we find no evidence for the existence of low-mass (M < 0.5 Mo) DB white dwarfs. We derive a luminosity function based on a subset of DB white dwarfs identified in the Palomar-Green survey. We show that 20% of all white dwarfs in the temperature range of interest are DB stars, although the fraction drops to half this value above Teff ~ 20,000 K. We also show that the persistence of DB stars with no hydrogen features at low temperatures is difficult to reconcile with a scenario involving accretion from the interstellar medium, often invoked to account for the observed hydrogen abundances in DBA stars. We present evidence for the existence of two different evolutionary channels that produce DB white dwarfs: the standard model where DA stars are transformed into DB stars through the convective dilution of a thin hydrogen layer, and a second channel where DB stars retain a helium-atmosphere throughout their evolution. We finally demonstrate that the instability strip of pulsating V777 Her white dwarfs contains no nonvariables, if the hydrogen content of these stars is properly accounted for.Comment: 74 pages including 30 figures, accepted for publication in the Astrophysical Journa

A Prototype Hail Detection Algorithm and Hail Climatology Developed with the Advanced Microwave Sounding Unit (AMSU)

In previous studies published in the open literature, a strong relationship between the occurrence of hail and the microwave brightness temperatures (primarily at 37 and 85 GHz) was documented. These studies were performed with the Nimbus7 SMMR, the TRMM Microwave Imager (TMI) and most recently, the Aqua AMSRE sensor. This lead to climatologies of hail frequency from TMI and AMSRE, however, limitations include geographical domain of the TMI sensor (35 S to 35 N) and the overpass time of the Aqua satellite (130 am/pm local time), both of which reduce an accurate mapping of hail events over the global domain and the full diurnal cycle. Nonetheless, these studies presented exciting, new applications for passive microwave sensors. Since 1998, NOAA and EUMETSAT have been operating the AMSUA/B and the MHS on several operational satellites: NOAA15 through NOAA19; MetOpA and B. With multiple satellites in operation since 2000, the AMSU/MHS sensors provide near global coverage every 4 hours, thus, offering a much larger time and temporal sampling than TRMM or AMSRE. With similar observation frequencies near 30 and 85 GHz and additionally three at the 183 GHz water vapor band, the potential to detect strong convection associated with severe storms on a more comprehensive time and space scale exists. In this study, we develop a prototype AMSUbased hail detection algorithm through the use of collocated satellite and surface hail reports over the continental U.S. for a 12year period (20002011). Compared with the surface observations, the algorithm detects approximately 40 percent of hail occurrences. The simple threshold algorithm is then used to generate a hail climatology that is based on all available AMSU observations during 200011 that is stratified in several ways, including total hail occurrence by month (March through September), total annual, and over the diurnal cycle. Independent comparisons are made compared to similar data sets derived from other satellite, ground radar and surface reports. The algorithm was also applied to global land measurements for a single year and showed close agreement with other satellite based hail climatologies. Such a product could serve as a prototype for use with a future geostationary based microwave sensor such as NASA's proposed PATH mission

The Relationship Between Task Cohesion and Competitive State Anxiety

The general purpose of the present study was to determine if perceptions of team cohesion are related to the interpretation athletes attach to their precompetition anxiety. Specifically examined was the association between athlete perceptions of task cohesiveness (Individual Attractions to the Group–Task, ATG-T, and Group Integration–Task, GI-T) and the degree to which perceptions of the intensity of precompetition anxiety symptoms (cognitive and somatic) were viewed as facilitative versus debilitative. Participants were athletes (N = 392) from the sports of soccer, rugby, and field hockey. Each athlete completed the Group Environment Questionnaire (Carron, Widmeyer, & Brawley, 1985) after a practice session. A directionally modified version of the Competitive State Anxiety Inventory-2 (Martens, Burton, Vealey, Bump, & Smith, 1990) was completed just prior to a competition. Results showed that athletes who perceived their cognitive anxiety as facilitative had higher perceptions of both ATG-T and GI-T, χ2 (2, N = 260) = 8.96, p \u3c .05, than athletes who perceived their cognitive anxiety as debilitative. Also, athletes who perceived their somatic anxiety as facilitative had higher perceptions of GI-T, χ2 (2, N = 249) = 5.85, p \u3c .05

Interfacial Reactions of Ozone with Surfactant Protein B in a Model Lung Surfactant System

Oxidative stresses from irritants such as hydrogen peroxide and ozone (O_3) can cause dysfunction of the pulmonary surfactant (PS) layer in the human lung, resulting in chronic diseases of the respiratory tract. For identification of structural changes of pulmonary surfactant protein B (SP-B) due to the heterogeneous reaction with O_3, field-induced droplet ionization (FIDI) mass spectrometry has been utilized. FIDI is a soft ionization method in which ions are extracted from the surface of microliter-volume droplets. We report structurally specific oxidative changes of SP-B_(1−25) (a shortened version of human SP-B) at the air−liquid interface. We also present studies of the interfacial oxidation of SP-B_(1−25) in a nonionizable 1-palmitoyl-2-oleoyl-sn-glycerol (POG) surfactant layer as a model PS system, where competitive oxidation of the two components is observed. Our results indicate that the heterogeneous reaction of SP-B_(1−25) at the interface is quite different from that in the solution phase. In comparison with the nearly complete homogeneous oxidation of SP-B_(1−25), only a subset of the amino acids known to react with ozone are oxidized by direct ozonolysis in the hydrophobic interfacial environment, both with and without the lipid surfactant layer. Combining these experimental observations with the results of molecular dynamics simulations provides an improved understanding of the interfacial structure and chemistry of a model lung surfactant system subjected to oxidative stress

Making sense of humour among men in a weight-loss program: A dialogical narrative approach

Humour appears to be an important aspect of health-promoting efforts for some men. A better understanding of the role humour plays in men’s health contexts may provide insight into the optimal design of health interventions for men. In this study, we explored the role banter, humour that blurs the line between playfulness and aggression, plays for men in a men’s weight loss context. We applied dialogical narrative analysis to thirty interviews conducted with men involved in a men’s weight-loss program that leverages competition to drive weight loss. Banter served several functions for men in the program, including allowing them to determine their social position during early group formation, feel good, develop camaraderie, experience respite, provide male inter-personal support in a counter-intuitive way, and ‘be themselves’. Men could use banter as a tool to develop resilience for themselves, but could also adapt their approach to use banter as a means of providing support for others. Banter could also cause trouble, through conflict and misunderstandings, primarily understood through a lens of narratives of progressiveness, inclusiveness, and a ‘changing culture’. Banter could do harm, by positioning oneself against certain characteristics, and as a tool to get under people’s skin. However, an approach-orientation to one’s problems may allow misunderstandings that arise due to banter to lead to enhanced group cohesion. Intervention developers ought to explicitly address the potential for banter (and humour more broadly) to have positive and negative effects in men’s health contexts

Designer Reagents for Mass Spectrometry-Based Proteomics: Clickable Cross-Linkers for Elucidation of Protein Structures and Interactions

We present novel homobifunctional amine-reactive clickable cross-linkers (CXLs) for investigation of three-dimensional protein structures and protein–protein interactions (PPIs). CXLs afford consolidated advantages not previously available in a simple cross-linker, including (1) their small size and cationic nature at physiological pH, resulting in good water solubility and cell-permeability, (2) an alkyne group for bio-orthogonal conjugation to affinity tags via the click reaction for enrichment of cross-linked peptides, (3) a nucleophilic displacement reaction involving the 1,2,3-triazole ring formed in the click reaction, yielding a lock-mass reporter ion for only clicked peptides, and (4) higher charge states of cross-linked peptides in the gas-phase for augmented electron transfer dissociation (ETD) yields. Ubiquitin, a lysine-abundant protein, is used as a model system to demonstrate structural studies using CXLs. To validate the sensitivity of our approach, biotin-azide labeling and subsequent enrichment of cross-linked peptides are performed for cross-linked ubiquitin digests mixed with yeast cell lysates. Cross-linked peptides are detected and identified by collision induced dissociation (CID) and ETD with linear quadrupole ion trap (LTQ)-Fourier transform ion cyclotron resonance (FTICR) and LTQ-Orbitrap mass spectrometers. The application of CXLs to more complex systems (e.g., in vivo cross-linking) is illustrated by Western blot detection of Cul1 complexes including known binders, Cand1 and Skp2, in HEK 293 cells, confirming good water solubility and cell-permeability

A microfluidic-based bubble generation platform enables analysis of physical property change in phospholipid surfactant layers by interfacial ozone reaction

The air-liquid interface filled with pulmonary surfactant is a unique feature of our lung alveoli. The mechanical properties of this interface play an important role in breathing and its malfunction induced by an environmental hazard, such as ozone, relates to various lung diseases. In order to understand the interfacial physics of the pulmonary surfactant system, we employed a microfluidic bubble generation platform with a model pulmonary surfactant composed of two major phospholipids: DPPC (1,2-dipalmitoyl-sn-phosphatidylcholine) and POPG (1-palmitoyl-2-oleoyl-sn-phosphatidylglycerol). With fluorescence imaging, we observed the ozone-induced chemical modification of the unsaturated lipid component of the lipid mixture, POPG. This chemical change due to the oxidative stress was further utilized to study the physical characteristics of the interface through the bubble formation process. The physical property change was evaluated through the oscillatory behaviour of the monolayer, as well as the bubble size and formation time. The results presented demonstrate the potential of this platform to study interfacial physics of lung surfactant system under various environmental challenges, both qualitatively and quantitatively